Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
نویسندگان
چکیده
منابع مشابه
Transition-metal-centered monocyclic boron wheel clusters (M©Bn): a new class of aromatic borometallic compounds.
Atomic clusters have intermediate properties between that of individual atoms and bulk solids, which provide fertile ground for the discovery of new molecules and novel chemical bonding. In addition, the study of small clusters can help researchers design better nanosystems with specific physical and chemical properties. From recent experimental and computational studies, we know that small bor...
متن کاملsynthesis of some new polycyclic aromatic monocyclic β-lactams
in this paper the synthesis of some new polyaromatic monocyclic β-lactams has been reported. these cycloadducts have been synthesized by the [2+2] ketene-imine cycloaddition reaction known as the staudinger reaction. all of the products have been fully characterized by ir, 1h-nmr, 13c-nmr, mass spectroscopy and elemental analyses. the x-ray crystal structure of a cis β-lactam has been also pres...
متن کاملBacterial degradation of monocyclic aromatic amines
Aromatic amines are an important group of industrial chemicals, which are widely used for manufacturing of dyes, pesticides, drugs, pigments, and other industrial products. These compounds have been considered highly toxic to human beings due to their carcinogenic nature. Three groups of aromatic amines have been recognized: monocyclic, polycyclic, and heterocyclic aromatic amines. Bacterial de...
متن کاملForming aromatic hemispheres on transition-metal surfaces.
This study details a new method to create materials by integrating polycyclic aromatic hydrocarbons into reactive transition-metal surfaces. We describe the interaction of hexabenzocoronene (1, HBC, Figure 1a) with a clean ruthenium surface. Interest in 1 and its interaction with transition-metal surfaces is driven by its relationship to the end cap of a carbon nanotube, to polynuclear aromatic...
متن کاملSynthesis of transition-metal polyphosphides
This dissertation describes the synthesis of several transition-metal polyphosphides including orthorhombic FeP2, cubic CoP3, cubic NiP2, monoclinic PdP2 and monoclinic CuP2. The investigation of these materials was initiated by the discovery of MPx formation upon reacting a metal halide with molecular yellow P4 in superheated toluene. When these MPx products were annealed at moderate temperatu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Reviews
سال: 2013
ISSN: 0009-2665,1520-6890
DOI: 10.1021/cr300333u